Crystal structure of [N,N-bis(diphenylphosphorothioyl)amidato-κ2 S,S′]bis(triphenylphosphane-κP)copper(I) dichloromethane monosolvate
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چکیده
The title compound, [Cu(C24H20NP2S2)(C18H15P)2]·CH2Cl2 or [Cu(dppaS2)(PPh3)2]·CH2Cl2, is a neutral mononuclear copper(I) complex bearing an N,N-bis-(di-phenyl-phospho-rothio-yl)amidate (dppaS2-) ligand and two tri-phenyl-phosphane ligands. The molecular structure shows that the two S atoms of the dppaS2- ligand [Cu-S = 2.3462 (9) and 2.3484 (9) Å] and the two P atoms of the two tri-phenyl-phosphane ligands [Cu-P = 2.3167 (9) and 2.2969 (9) Å] coordinate to the copper(I) atom, resulting in a tetra-hedral coordination geometry. The crystallographically observed mol-ecular structure is compared to the results of DFT calculations.
منابع مشابه
Crystal structure of [1-(2,6-diisopropylphenyl)-2,4-bis(dimethylamino)-5-trimethylsilyl-1,3,5-triazapentadienyl-κ2 N 1,N 5](triphenylphosphane-κP)copper(I)
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